Effects of debris-flow and bed composition on erosion and entrainment

Erosion and entrainment of material by debris flows determine debris-flow volume growth and therefore hazard potential. Recent advances in field, laboratory, and modelling studies have distilled two driving forces behind debris-flow erosion; impact and shear forces. A third factor influencing the (relative) importance of these forces is the viscosity and abundance of the interstitial fluid in the debris flow and the bed. However, how erosion and these forces depend on the composition of the debris flow itself and the composition of the bed remains unclear. Here, we present results of small-scale flume experiments with a loosely packed erodible bed that highlight the far-reaching effects of debris-flow and bed composition on erosion processes and magnitude. We quantify the effects of gravel, clay, and solid fraction in the debris flow on bed erosion. In addition, we quantify the effects of water and clay content of the unconsolidated bed on erosion by a debris flow. We show that debris flow erosion increases linearly when the gravel fraction of a debris flow is increased, which is linked to an increase in both impact and shear forces. We find that debris flow erosion, and the related forces, are non-linearly impacted by the clay and water content of the debris flow and those of the bed. For both the clay content of the debris flow and the bed, an optimum in erosion exists around a specific clay percentage that does not directly relate to an optimum in either shear or impact forces. When the water content of the bed and/or the debris flow is increased, erosion becomes largest when supersaturated conditions occur. These conditions are unrelated to the magnitude of the two erodible forces. This shows that both clay and water content affect erosion by affecting the transfer of pore pressures from the debris flow to the bed. We can therefore conclude that impact and shear forces dictate debris flow erosion in most cases but that their (relative) importance is significantly altered by the means and effectivity of pore pressure transfer from the debris flow to the bed. The latter is highly influenced by the viscosity and abundance of the interstitial fluid of the debris flow and the composition of the bed

How Bed Composition Affects Erosion by Debris Flows - An Experimental Assessment

A solid physical understanding of debris-flow erosion is needed for both hazard prediction and understanding landscape evolution. However, the processes and forces involved in erosion by debris flows and especially how the erodible surface itself influences erosion are poorly understood. Here, we experimentally investigate the effects of bed composition on debris-flow erosion, by systematically varying the composition of an erodible bed in a small-scale debris-flow flume. The experiments show that water and clay content of an unconsolidated bed significantly control erosion magnitude by affecting the transfer of pore pressure, loading conditions, and contraction-dilation behavior of the bed. As the water content increases and the bed comes close to saturation, erosion increases rapidly, whereas for clay content an optimum for erosion exists around a clay content of 3%–4%. Our results show that small variations in bed composition can have large effects on debris-flow erosion, and thus volume growth and hazard potential

How debris‐flow composition affects bed erosion quantity and mechanisms: An experimental assessment

Understanding erosion and entrainment of material by debris flows is essential for predicting and modelling debris-flow volume growth and hazard potential. Recent advances in field, laboratory and modelling studies have distilled two driving forces behind debris-flow erosion: impact and shear forces. How erosion and these forces depend on debris-flow composition and interact remains unclear. Here, we experimentally investigate the effects of debris-flow composition and volume on erosion processes in a small-scale flume with a loosely packed bed. We quantify the effects of gravel, clay and solid fraction in the debris flow on bed erosion. Erosion increased linearly with gravel fraction and volume, and decreased with increasing solid fraction. Erosion was maximal around a volumetric clay fraction of 0.075 (fraction of the total solid volume). Under varying gravel fractions and flow volumes erosion was positively related to both impact and shear forces, while these forces themselves are also correlated. Results further show that internal dynamics driving the debris flows, quantified by Bagnold and Savage numbers, correlate with erosional processes and quantity. Impact forces became increasingly important for bed erosion with increasing grain size. The experiments with varying clay and solid fractions showed that the abundance and viscosity of the interstitial fluid affect debris-flow dynamics, erosional mechanisms and erosion magnitude. High viscosity of the interstitial fluid inhibits the mobility of the debris flow, the movement of the individual grains and the transfer of momentum to the bed by impacts, and therefore inhibits erosion. High solid content possibly decreases the pore pressures in the debris flow and the transport capacity, inhibiting erosion, despite high shear stresses and impact forces. Our results show that bed erosion quantities and mechanisms may vary between debris flows with contrasting composition, and stress that entrainment models and volume-growth predictions may be substantially improved by including compositional effects

Effects of debris-flow and bed composition on erosion and entrainment

Erosion and entrainment of material by debris flows determine debris-flow volume growth and therefore hazard potential. Recent advances in field, laboratory, and modelling studies have distilled two driving forces behind debris-flow erosion; impact and shear forces. A third factor influencing the (relative) importance of these forces is the viscosity and abundance of the interstitial fluid in the debris flow and the bed. However, how erosion and these forces depend on the composition of the debris flow itself and the composition of the bed remains unclear. Here, we present results of small-scale flume experiments with a loosely packed erodible bed that highlight the far-reaching effects of debris-flow and bed composition on erosion processes and magnitude. We quantify the effects of gravel, clay, and solid fraction in the debris flow on bed erosion. In addition, we quantify the effects of water and clay content of the unconsolidated bed on erosion by a debris flow. We show that debris flow erosion increases linearly when the gravel fraction of a debris flow is increased, which is linked to an increase in both impact and shear forces. We find that debris flow erosion, and the related forces, are non-linearly impacted by the clay and water content of the debris flow and those of the bed. For both the clay content of the debris flow and the bed, an optimum in erosion exists around a specific clay percentage that does not directly relate to an optimum in either shear or impact forces. When the water content of the bed and/or the debris flow is increased, erosion becomes largest when supersaturated conditions occur. These conditions are unrelated to the magnitude of the two erodible forces. This shows that both clay and water content affect erosion by affecting the transfer of pore pressures from the debris flow to the bed. We can therefore conclude that impact and shear forces dictate debris flow erosion in most cases but that their (relative) importance is significantly altered by the means and effectivity of pore pressure transfer from the debris flow to the bed. The latter is highly influenced by the viscosity and abundance of the interstitial fluid of the debris flow and the composition of the bed

How debris‐flow composition affects bed erosion quantity and mechanisms: An experimental assessment

Understanding erosion and entrainment of material by debris flows is essential for predicting and modelling debris-flow volume growth and hazard potential. Recent advances in field, laboratory and modelling studies have distilled two driving forces behind debris-flow erosion: impact and shear forces. How erosion and these forces depend on debris-flow composition and interact remains unclear. Here, we experimentally investigate the effects of debris-flow composition and volume on erosion processes in a small-scale flume with a loosely packed bed. We quantify the effects of gravel, clay and solid fraction in the debris flow on bed erosion. Erosion increased linearly with gravel fraction and volume, and decreased with increasing solid fraction. Erosion was maximal around a volumetric clay fraction of 0.075 (fraction of the total solid volume). Under varying gravel fractions and flow volumes erosion was positively related to both impact and shear forces, while these forces themselves are also correlated. Results further show that internal dynamics driving the debris flows, quantified by Bagnold and Savage numbers, correlate with erosional processes and quantity. Impact forces became increasingly important for bed erosion with increasing grain size. The experiments with varying clay and solid fractions showed that the abundance and viscosity of the interstitial fluid affect debris-flow dynamics, erosional mechanisms and erosion magnitude. High viscosity of the interstitial fluid inhibits the mobility of the debris flow, the movement of the individual grains and the transfer of momentum to the bed by impacts, and therefore inhibits erosion. High solid content possibly decreases the pore pressures in the debris flow and the transport capacity, inhibiting erosion, despite high shear stresses and impact forces. Our results show that bed erosion quantities and mechanisms may vary between debris flows with contrasting composition, and stress that entrainment models and volume-growth predictions may be substantially improved by including compositional effects

1994 Merck Frosst Award Lecture new strategies for the stereoselective synthesis of natural and unnatural products via organometallic reagents and catalysts

Samarium in the presence of diiodomethane selectively cyclopropanates an allenic alcohol to yield a methylenecyclopropane with modest to excellent diastereoselectivity. The effect of substituents at the carbinol carbon and the allenic carbon on the diastereoselectivity was investigated. A palladium catalyst was shown to promote the intramolecular cycloaddition of the methylenecyclopropane with an electron-deficient alkyne to yield a methylenecyclopentane. The reaction was stereospecific with retention of stereochemistry as proven by X-ray diffraction. Nickel catalysts accelerate the hydroalumination of oxabicyclo[3.2.1]alkenes, leading to bicyclic trialkylalanes. Upon treatment with a Lewis acid (diisobutylaluminum chloride), the trialkylalanes fragment to provide cycloheptenols. This reaction, followed by an enantioselective enzyme-catalyzed esterification, was used as a key step in a synthesis of the mevinic acid lactone.link_to_subscribed_fulltex